导师信息#北京理工大学化学学院研究生导师介绍#姚波

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基本信息:
姓名咨询QQ、微信：2544906反应中的作用机制以及对活性催化物种的影响。最后，在反应研究和机理研究的基础上，发展了一种低催化剂上载量的绿色催化方法。
（2）在高价有机铜化学方面，利用所设计的新型大环配体，制备了一类结构新颖的室温下稳定的有机三价铜化合物，首次发现和报道了有机三价铜化合物与阴离子型亲核试剂的高效反应。通过对有机三价铜的结构、反应性质和形成机理进行系统研究，展示了三价铜独特的结构和反应性质，填补了人们对高价铜认识的不足。在此基础上，设计并发展了一种室温下铜催化的碳氢键直接功能化的反应，为研究铜催化有机反应的机理和新反应设计提供新思路。迄今为止以第一作者或共同第一作者在J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Chem. Eur. J.等国际学术期刊上发表高质量学术论文12篇。
发表论文：
1.Hu Zhang,† Bo Yao,† Liang Zhao, De-Xian Wang, Bo-Qing Xu, Mei-Xiang Wang*, “Direct Synthesis of High-Valent Aryl-Cu(II) and Aryl-Cu(III) Compounds: Mechanistic Insight into Arene C-H Bond Metalation”, J. Am. Chem. Soc. 2014, 136, 63266332.（†共同第一作者）
2.Bo Yao, Qian Wang, Jieping Zhu*, “Pd(II)-Catalyzed Cyclizative Cross Coupling of ortho-Alkynylanilines with ortho-Alkynylbenzamides under Aerobic Conditions”, Angew. Chem. Int. Ed. 2013, 52, 1299212996. (Highlighted by Chimia 2014, 68, 183).
3.Bo Yao, Qian Wang, Jieping Zhu*, “Palladium-Catalyzed Coupling of ortho-Alkynylanilines with Terminal Alkynes Under Aerobic Conditions: Efficient Synthesis of 2,3-Disubstituted 3-Alkynylindoles”, Angew. Chem. Int. Ed. 2012, 51, 12311-12315. (Highlighted by Synfacts: 2013, 9, 475).
4.Bo Yao, Qian Wang, Jieping Zhu*, “Palladium(II)-Catalyzed Intramolecular Diamination of Alkynes under Aerobic Oxidative Conditions: Catalytic Turnover of an Iodide Ion”, Angew. Chem. Int. Ed. 2012, 51, 5170-5174.
5.Tu M. Ha,† Bo Yao,† Qian Wang, Jieping Zhu*, “2-(Methoxycarbonyl)ethyl as a Removable N-Protecting Group: Synthesis of Indoloisoquinolinones by Pd(II)-Catalyzed Intramolecular Diamination of Alkynes”, Org. Lett. 2015, 17, 1750–1753.（†共同第作者）
6.Bo Yao, Qian Wang, Jieping Zhu*, “Pd/C-Catalyzed Cyclizative Cross-Coupling of Two ortho-Alkynylanilines under Aerobic Conditions: Synthesis of 2,3'-Bisindoles”, Chem. Eur. J. 2015, 21, 7413–7416.
7.Bo Yao, Qian Wang, Jieping Zhu*, “Mechanistic Study on the Palladium(II)-Catalyzed Synthesis of 2,3-Disubstituted Indoles Under Aerobic Conditions: Anion Effects and the Development of a Low-Catalyst-Loading Process”, Chem. Eur. J. 2014, 20,12255–12261.
8.Bo Yao, Yang Liu, Liang Zhao，Mei-Xiang Wang*, “Designing a Cu(II)–ArCu(II)–ArCu(III)–Cu(I) Catalytic Cycle: Cu(II)-Catalyzed Oxidative Arene C–H Bond Azidation with Air as an Oxidant under Ambient Conditions”, J. Org. Chem. 2014, 79, 1113911145.
9. Bo Yao, De-Xian Wang, Zhi-Tang Huang, Mei-Xiang Wang*, “Room-temperature Aerobic Formation of a Stable Aryl–Cu(III) Complex and Its Reactions with Nucleophiles: Highly Efficient and Diverse Arene C–H Functionalizations of Azacalix[1]arene[3pyridine”, Chem. Commun. 2009, 2899-2901.
10.Bo Yao, Carole Jaccoud, Qian Wang, Jieping Zhu*, “Synergistic Effect of Palladium and Copper Catalysts: Catalytic Cyclizative Dimerization of ortho-(1-Alkynyl)benzamides Leading to Axially Chiral 1,3-Butadienes”, Chem. Eur. J. 2012, 18, 5864-5868.(Highlighted by Chimia 2012, 66, 442).
11.Bo Yao, Zu-Li Wang, Hu Zhang, De-Xian Wang, Liang Zhao, Mei-Xiang Wang*, “Cu(ClO4)2-Mediated Arene C−H Bond Halogenations of Azacalixaromatics Using Alkali Metal Halides as Halogen Sources”, J. Org. Chem. 2012, 77, 3336-3340.
12.Bo Yao, De-Xian Wang, Han-Yuan Gong, Zhi-Tang Huang, Mei-Xiang Wang*, “Synthesis, Structure, and Reactions of NH-Bridged Calix[m]arene[n]pyridines”, J. Org. Chem. 2009, 74, 5361-5368.